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sigma6
23rd November 2014, 09:19
Fools Gold May Be a Solar Material
http://www.engineering.com/DesignerEdge/DesignerEdgeArticles/ArticleID/9000/Engineers-May-Have-Struck-it-Rich-Fools-Gold-May-Be-a-Solar-Material.aspx


...Theoretically, iron pyrite -- a cheap compound that makes a common mineral known as fool's gold -- could do the job, but when it works at all, the conversion efficiency remains frustratingly low. Now, a University of Wisconsin-Madison research team explains why that is, in a discovery that suggests how improvements in this promising material could lead to inexpensive yet efficient solar cells.

"We think we now understand why pyrite hasn't worked," says chemistry Professor Song Jin, "and that provides the hope, based on our understanding, for figuring out how to make it work. This could be even more difficult, but exciting and rewarding..."

Tesla_WTC_Solution
23rd November 2014, 17:54
That's remarkable!

http://www.sciencedirect.com/science/article/pii/
Iron pyrite FeS2 for flexible solar cells

B. Reziga,
H. Dahman∗, a,
M. Kenzaria

Abstract

We used the vacuum thermal evaporation technique to grow iron thin films on heated glass substrates. Thick fresh iron layers (1000–3000 Å) sulfurized under nitrogen flux were converted into iron pyrite FeS2 phase identified by X-ray study.

Reproducible 1–2 kω (10−2 ω-cm) FeS2 layers showed P type coductivity. Nevertheless, iron films previously oxidized showed N type behaviour when submitted to the same sulfurization process. Optical transmission measurements had been carried out on several thicknesses before and after layer conversion. The results confirmed the highly absorbing character of the pyrite FeS2 and also the presence, in the explored spectral range (UV-Visible) of two competitive transitions: the first at 1.31 eV (indirect gap) abd the second at 1.45 eV (direct gap). Some interpretations are given concerning the origin of the opacity of the FeS2 obtained from Fe films. Comparison is made with iron pyrite results obtained by spray pyrolysis as reported by some workers.

Copyright © 1992 Published by Elsevier Ltd.




http://cdn.intechopen.com/pdfs-wm/39155.pdf

Thin Film Solar Cells Using Earth-Abundant Materials
Parag S. Vasekar and Tara P. Dhakal

avid
23rd November 2014, 18:03
I have forwarded this info, and thank you so much for your input.

DeDukshyn
23rd November 2014, 18:57
Very cool stuff!